Ethylene Glycol - SDS
Safety Data Sheet (SDS)
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. Date of Issue: 04/04/2016.
Download Ethylene Glycol Safety Data Sheet (SDS) here 
SECTION 1: IDENTIFICATION
1.1. Product Identifier
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Product Form: Substance |
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Product Name: Ethylene Glycol |
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CAS-No.: 107-21-1 |
1.2. Intended Use of the Product: Industrial chemical
1.3. Name, Address, and Telephone of the Responsible Party
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Company High Precision Gas LLC |
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1.4. Emergency Telephone Number
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Emergency Number |
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Professional Emergency Resource Services (PERS) |
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the Substance or Mixture
GHS-US classification
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Flam. Liq. 2 |
H302 |
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Acute Tox. 3 (oral) |
H373 |
Full text of hazard classes and H-statements : see section 16
2.2. Label Elements
GHS-US Labeling
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Hazard Pictograms (GHS-US) |
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 GHS07 |
 GHS07 |
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Signal Word (GHS-US) |
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Warning |
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Hazard Statements (GHS-US) |
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H302 – Harmful if swallowed. H373 – May cause damage to organs (kidney) through prolonged or repeated exposure (if swallowed) |
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Precautionary Statements (GHS-US) |
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P260 – Do not breathe dust / fume / gas / mist / vapors / spray P264 – Wash skin thoroughly after handling P270 – Do not eat, drink or smoke when using this product P301+P312+P330 – If swallowed, call a poison center / doctor if you feel unwell. Rinse mouth. P314 – Get medial advice / attention if you feel unwell P501 - Dispose of contents/container to approved waste disposal plant in accordance with local, regional, national, and international regulations. |
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2.3. Other Hazards
No additional information.
2.4. Unknown Acute Toxicity (GHS-US)
No data available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substance
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Name |
Synonyms |
Product Identifier |
% |
GHS US classification |
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Ethanediol |
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(CAS-No.) 107-21-1 |
100 |
Acute Tox. 4 (Oral): H302 STOT RE 2: H373 |
Full text of H-phrases: see section 16
SECTION 4: FIRST AID MEASURES
4.1. Description of First-aid Measures
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First-aid Measures General: Move out of dangerous area. Take off contaminated clothing. |
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First-aid Measures After Inhalation: When symptoms occur: go into open air and ventilate suspected area. Obtain medical attention if symptoms persists. |
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First-aid Measures After Skin Contact: Immediately drench affected area with water for at least 15 minutes. Immediately remove contaminated clothing. If exposed or concerned: Get medical advice/attention. |
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First-aid Measures After Eye Contact: Immediately rinse with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if irritation develops or persists. |
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First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Obtain medical attention. |
4.2. Most Important Symptoms and Effects Both Acute and Delayed
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Symptoms/Injuries: May cause drowsiness, dizziness, fatigue, vertigo, agitation, diarrheoa, vomiting, nausea and unconsciousness. |
4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed
None.
SECTION 5: FIRE-FIGHTING MEASURES
5.1. Extinguishing Media
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Suitable Extinguishing Media: Dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). Water may be ineffective but water should be used to keep fire-exposed container cool. |
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Unsuitable Extinguishing Media: Do not use a heavy water stream such as water jet. A heavy water stream may spread burning liquid. |
5.2. Special Hazards Arising From the Substance or Mixture
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Fire Hazard: Highly flammable (conbustible) liquid and vapor. |
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Explosion Hazard: May form flammable or explosive vapor-air mixture. |
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Reactivity: Reacts violently with strong oxidizers. Increased risk of fire or explosion. |
5.3. Advice for Firefighters
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Precautionary Measures Fire: Exercise caution when fighting any chemical fire. |
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Firefighting Instructions: Use water spray or fog for cooling exposed containers. In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. |
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Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. |
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Hazardous Combustion Products: Carbon oxides (CO, CO2). |
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Other Information: Do not allow run-off from fire fighting to enter drains or water courses. |
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal Precautions, Protective Equipment and Emergency Procedures
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General Measures: Do not breathe vapor, mist or spray. Do not get in eyes, on skin, or on clothing. Do not handle until all safety precautions have been read and understood. Keep away from heat, hot surfaces, sparks, open flames, and other ignition sources. No smoking. Use special care to avoid static electric charges. |
6.1.1. For Non-Emergency Personnel
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Protective Equipment: Use appropriate personal protective equipment (PPE). |
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Emergency Procedures: Evacuate unnecessary personnel. Stop leak if safe to do so. |
6.1.2. For Emergency Personnel
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Protective Equipment: Equip cleanup crew with proper protection. |
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Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit. Ventilate area. Eliminate ignition sources. |
6.2. Environmental Precautions
Prevent entry to sewers and public waters. Avoid release to the environment. Collect spillage.
6.3. Methods and Materials for Containment and Cleaning Up
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For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. As an immediate precautionary measure, isolate spill or leak area in all directions. |
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Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Transfer spilled material to a suitable container for disposal. Contact competent authorities after a spill. Absorb and/or contain spill with inert material. Do not take up in combustible material such as: saw dust or cellulosic material. Use only non-sparking tools. |
6.4. Reference to Other Sections
See Section 8 for exposure controls and personal protection and Section 13 for disposal considerations.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for Safe Handling
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Additional Hazards When Processed: Handle empty containers with care because residual vapors are flammable. |
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Precautions for Safe Handling: Avoid contact with skin, eyes and clothing. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe mist, spray, vapors. Take precautionary measures against static discharge. Use only non-sparking tools. |
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Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. |
7.2. Conditions for Safe Storage, Including Any Incompatibilities
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Technical Measures: Comply with applicable regulations. Take action to prevent static discharges. Ground and bond container and receiving equipment. Use explosion-proof electrical, ventilating, and lighting equipment. |
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Storage Conditions: Store in a dry, cool place. Keep/Store away from direct sunlight, extremely high or low temperatures and incompatible materials. Store locked up/in a secure area. Store in a well-ventilated place. Keep container tightly closed. Keep in fireproof place. |
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Incompatible Materials: Strong acids, strong bases, strong oxidizers. |
7.3. Specific End Use(s) No additional information available
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control Parameters
For substances listed in section 3 that are not listed here, there are no established exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), AIHA (WEEL), NIOSH (REL), or OSHA (PEL).
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Ethylene Glycol (107-21-1) |
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USA ACGIH |
ACGIH C (ppm) |
50 ppm |
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USA ACGIH |
ACGIH (C) (mg/m³) |
100 mg/m³ |
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USA OSHA |
OSHA PEL (C) (ppm) |
50 ppm |
8.2. Exposure Controls
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Appropriate Engineering Controls |
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Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas. Ensure all national/local regulations are observed. Gas detectors should be used when flammable gases or vapors may be released. Proper grounding procedures to avoid static electricity should be followed. Use explosion-proof equipment. |
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Personal Protective Equipment |
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Gloves. Protective clothing. Protective goggles. Insufficient ventilation: wear respiratory protection.
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| Materials for Protective Clothing | : | Chemically resistant materials and fabrics. Wear fire/flame resistant/retardant clothing. |
| Hand Protection | : | Wear protective gloves. |
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Eye and Face Protection |
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Chemical safety goggles. |
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Skin and Body Protection |
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Wear suitable protective clothing. |
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Respiratory Protection |
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If exposure limits are exceeded or irritation is experienced, approved respiratory protection should be worn. In case of inadequate ventilation, oxygen deficient atmosphere, or where exposure levels are not known wear approved respiratory protection. |
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Other Information |
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When using, do not eat, drink or smoke. |
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on Basic Physical and Chemical Properties
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Physical State |
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Liquid |
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Appearance |
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Clear, Colorless – light yellow |
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Odor |
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Odorless |
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Odor Threshold |
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No data available |
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pH |
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9 |
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Evaporation Rate |
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No data available |
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Melting Point |
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-14 – -12 °C at 1.013 hPa |
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Freezing Point |
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-13 - -11.2 °C (9 - 11.8 °F) |
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Boiling Point |
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197.4 °C (387.3 °F) |
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Flash Point |
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111 - 116 °C (232 - 241 °F) |
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Auto-ignition Temperature |
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398 °C |
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Decomposition Temperature |
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No data available |
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Flammability (solid, gas) |
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No data available |
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Vapor Pressure |
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<1 hPa @ 20 - 25 °C (68 - 77 °F) |
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Relative Vapor Density at 20°C |
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No data available |
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Relative Density |
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1.11 g/cm3 @ 20 °C (68 °F) |
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Solubility |
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Soluble |
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Partition Coefficient: N-Octanol/Water |
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log Pow: -1.36 |
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Viscosity |
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Dynamic - 19.83 - 21 mPa.s @ 20 - 25 °C (68 - 77 °F) Kinematic - 145 mm2/s @ 25 °C (77 °F) |
9.2. Other Information: No additional information available.
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity: No dangerous reaction know under conditions of normal use.
10.2. Chemical Stability: Stable under normal conditions.
10.3. Possibility of Hazardous Reactions: No hazards to be specially mentioned.
10.4. Conditions to Avoid: Direct sunlight, extremely high or low temperatures, heat, hot surfaces, sparks, open flames, incompatible materials, and other ignition sources.
10.5. Incompatible Materials: Strong bases, stong oxidizing agents, atong acids, aldehydes, aluminum, plastics, reducing agent and proxides.
10.6. Hazardous Decomposition Products: Aldehydes, ketones, organic acids and carbon oxides.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on Toxicological Effects
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Acute Toxicity: Not classified |
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Ethylene Glycol (107-21-1) |
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LD50 Oral Rat |
> 3500 mg/kg |
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LD50 Dermal Rat |
4.7 mg/kg |
Skin Corrosion/Irritation: Not classified.
Serious Eye Damage/Irritation: Not classified.
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Respiratory or Skin Sensitization: Not classified |
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Germ Cell Mutagenicity: Not classified. |
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Carcinogenicity: Not classified. |
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Reproductive Toxicity: Not classified. |
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Specific Target Organ Toxicity (Single Exposure): Not classified. |
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Specific Target Organ Toxicity (Repeated Exposure): May cause damage to organs (kidney) through prolonged or repeated exposure (if swallowed). |
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Aspiration Hazard: Not classified |
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Symptoms/Injuries After Inhalation: No data available. |
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Symptoms/Injuries After Skin Contact: Non-irritating. |
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Symptoms/Injuries After Eye Contact: Contact causes severe irritation with redness and swelling of the conjunctiva. |
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Symptoms/Injuries After Ingestion: Vomiting, nausea, liver and kidney damage. |
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Chronic Symptoms: No data available. Other information: Other adverse effects – loss of righting reflex, and ataxia, unconsciousness, drowsiness and agitation. |
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Acute Toxicity (oral): Toxic if swallowed. Acute Toxicity (dermal): Toxic if contact with skin. Acute Toxicity (inhalation): Toxic if inhaled. |
SECTION 12: ECOLOGICAL INFORMATION
12.1. Toxicity
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Ecology - General |
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Should not be classified as hazardous to aquatic enviroment. |
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Ethylene Glycol (107-21-1) |
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LC50 Fish 1 |
>72.860 mg/l (Exposure time: 96 h - Species: Cichlid fish) |
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EC50 Daphnia 1 |
> 100 mg/l |
12.2. Persistence and Degradability
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Ethylene Glycol (107-21-1) |
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Persistence and Degradability |
The substance is readily biodegradable. |
12.3. Bioaccumulative Potential
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Ethylene Glycol (107-21-1) |
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Bioaccumulative Potential |
Does not significantly accumulate in organisms. |
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Ethylene Glycol (107-21-1) |
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Log Pow |
-1.36 |
12.4. Mobility in Soil 0,013 Pa m³/mol at 25 °C
12.5. Other Adverse Effects
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Other Information |
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No data available. |
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste Treatment Methods
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Waste Disposal Recommendations: Dispose of contents/container in accordance with local, regional, national, and international regulations. Do not re-use empty containers. |
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Additional Information: Handle empty containers with care. Do not empty into drains |
| Ecology - Waste Materials: Avoid release to the environment. This material is hazardous to the aquatic environment. Keep out of sewers and waterways. |
SECTION 14: TRANSPORT INFORMATION
The shipping description(s) stated herein were prepared in accordance with certain assumptions at the time the SDS was authored, and can vary based on a number of variables that may or may not have been known at the time the SDS was issued.
14.1. In Accordance with DOT Not regulated
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Proper Shipping Name |
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ETHYLENE GLYCOL |
14.2. In Accordance with IMDG Not regulated
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Proper Shipping Name |
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ETHYLENE GLYCOL |
14.3. In Accordance with IATA Not regulated
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Proper Shipping Name |
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ETHYLENE GLYCOL |
SECTION 15: REGULATORY INFORMATION
15.1. US Federal Regulations
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Ethylene Glycol (107-21-1) |
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SARA Section 311/312 Hazard Classes |
Health hazard - Specific target organ toxicity (single or repeated exposure) |
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SARA Section 313 Reporting |
Component – Ethylene glycol CAS-No – 107-21-1 Weight% - >95 SARA 313 – Threshold Values % - 1.0 |
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CERCLA |
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) |
15.2. US State Regulations
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Ethylene Glycol (107-21-1) |
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U.S. - Massachusetts - Right To Know List U.S. – Illinois – Right to Know List |
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California Prop 65 |
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WARNING: This product can expose you to chemicals including 1,4-Dioxane, Acetaldehyde, which is/are known to the State of California to cause cancer, and Ethylene glycol, which is/are known to the State of California to cause birth defects or other reproductive harm. For more in-formation go to www.P65Warnings.ca.gov |
SECTION 16: OTHER INFORMATION
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Date of Preparation or Latest Revision |
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09/01/2019 |
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Other Information |
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This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200 |
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GHS Full Text Phrases: |
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Acute Tox. 4 (Oral) |
Acute toxicity (oral), Category 4 |
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STOT RE2 |
Specific target organ toxicity – Repeated exposure Category 2 |
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H302 |
Harmful if swallowed |
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H373 |
May cause damage to organs tthrough prolonged or repeated exposure |
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
SDS US (GHS HazCom)