Ethanol 200 Proof Non-Denatured - SDS

High Precision Gas

Safety Data Sheet (SDS)

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This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. Date of Issue: 04/04/2016.
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SECTION 1: IDENTIFICATION

1.1.       Product Identifier

Product Form: Mixture

Product Name: Ethyl Alcohol 200 Proof

CAS-No.: 64-17-5

1.2.       Intended Use of the Product  General purpose solvent

1.3.       Name, Address, and Telephone of the Responsible Party

Company  

High Precision Gas LLC
10770 Painter Avenue
Santa Fe Springs, CA 90670
714-868-6525
www.highprecisiongas.com

 

1.4.       Emergency Telephone Number  

Emergency Number

:

Professional Emergency Resource Services (PERS)
(800) 633-8253  24 / 7 / 365

 

SECTION 2: HAZARDS IDENTIFICATION

2.1.       Classification of the Substance or Mixture

GHS-US classification

Flam. Liq. 2

H225

Eye Irrit. 2

H319

2.2.       Label Elements

GHS-US Labeling

Hazard Pictograms (GHS-US)

:

GHS02

GHS07

 

 

Signal Word (GHS-US)

:

Danger

Hazard Statements (GHS-US)

:

H225 - HIGHLY FLAMMABLE LIQUID AND VAPOR
H319 - Causes serious eye irritation

Precautionary Statements (GHS-US)

:

P210 - Keep away from heat, open flames, sparks. - No smoking.
P233 - Keep container tightly closed.
P240 - Ground/bond container and receiving equipment.
P241 - Use explosion-proof electrical, lighting, ventilating equipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P264 - Wash hands, forearms, and exposed areas thoroughly after handling.
P280 - Wear eye protection, protective gloves, protective clothing.
P303+P361+P353 - IF ON SKIN (OR HAIR): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P303+P361+P353 - IF ON SKIN (OR HAIR): Take off immediately all contaminated clothing. Rinse with water/shower.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P370+P378 - In case of fire: Use appropriate media to extinguish.
P403+P235 - Store in a well-ventilated place. Keep cool.
P501 - Dispose of contents/container in accordance with local, regional, national, territorial, provincial, and international regulations

 

2.3.       Other Hazards 

Flammable vapors can accumulate in head space of closed systems.

2.4.       Unknown Acute Toxicity (GHS-US)

No data available

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1.       Substance

Name

Synonyms

Product Identifier

%

Ethyl alcohol

(CAS-No.) 64-17-5

100

 

 

SECTION 4: FIRST AID MEASURES

4.1.       Description of First-aid Measures  

First-aid Measures General:  Never give anything by mouth to an unconscious person. If exposed or concerned, seek medical advice (show the label where possible).

First-aid Measures After Inhalation:  When symptoms occur: go into open air and ventilate suspected area. Obtain medical attention if breathing difficulty persists.

First-aid Measures After Skin Contact:  Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical attention if irritation develops and persists.

First-aid Measures After Eye Contact:  Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists

First-aid Measures After Ingestion:  Rinse mouth. Get medical attention if symptoms occur.

4.2.       Most Important Symptoms and Effects Both Acute and Delayed 

General:  Causes serious eye irritation

Symptoms/Injuries After Inhalation:  Prolonged exposure to liquid may cause a mild irritation.

Symptoms/Injuries After Skin Contact:  Repeated or prolonged skin contact may cause dermatitis and defatting.

Symptoms/Injuries After Eye Contact:  Causes serious eye irritation. Symptoms may include: Redness, pain, swelling, itching, burning, tearing, and blurred vision.

Symptoms/Injuries After Ingestion:  Ingestion will cause narcotic effects including, but not limited to: nausea, vomiting, abdominal pain, dizziness, incoordination, and respiratory depression.

Chronic Symptoms:  None expected under normal conditions of use.

4.3.       Indication of Any Immediate Medical Attention and Special Treatment Needed  

If medical advice is needed, have product container or label at hand.

SECTION 5: FIRE-FIGHTING MEASURES

5.1.       Extinguishing Media 

Suitable Extinguishing Media:  Alcohol-resistant foam, carbon dioxide, dry chemical, water spray, fog.

Unsuitable Extinguishing Media:  Do not use a heavy water stream. A heavy water stream may spread burning liquid. Water may be ineffective because it may not cool material below its flash point.

5.2.       Special Hazards Arising From the Substance or Mixture 

Fire Hazard:  Highly flammable liquid and vapor.

Explosion Hazard:  May form flammable/explosive vapor-air mixture. When mixed with air and exposed to an ignition source, flammable vapors can burn in the open or explode in confined spaces. Being heavier than air, vapors may travel long distances to an ignition source and flash back. Runoff to sewer may cause fire or explosion hazard

Reactivity: Reacts violently with strong oxidizers. Increased risk of fire or explosion.

5.3.       Advice for Firefighters 

Precautionary Measures Fire:  Exercise caution when fighting any chemical fire. Under fire conditions, hazardous fumes will be present.

Firefighting Instructions:  Use water spray or fog for cooling exposed containers. Prevent fire-fighting water from entering environment..

Protection During Firefighting:  DANGER: Do not enter fire area without proper protective equipment, including respiratory protection.

Hazardous Combustion Products: Carbon oxides (CO, CO2).

 Refer to section 9 for flammability properties.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1.       Personal Precautions, Protective Equipment and Emergency Procedures

General Measures:  Use special care to avoid static electric charges. Keep away from heat, sparks, open flames, hot surfaces. – No smoking. Avoid all eyes and skin contact and do not breathe vapor and mist.

6.1.1.      For Non-Emergency Personnel: 

Protective Equipment: Use appropriate personal protective equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel. Stop leak if safe to do so.

 

6.1.2.      For Emergency Personnel:  

Protective Equipment:  Equip cleanup crew with proper protection.  Use appropriate protection equipment (PPE).

Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit.

6.2.       Environmental Precautions 

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3.       Methods and Materials for Containment and Cleaning Up 

For Containment:  Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams.

Methods for Cleaning Up:  Absorb and/or contain spill with inert material, then place in suitable container. Do not take up in combustible material such as: saw dust or cellulosic material. Use only non-sparking tools

 6.4.       Reference to Other Sections 

See Section 8 for exposure controls and personal protection.

 

SECTION 7: HANDLING AND STORAGE

7.1.       Precautions for Safe Handling 

Additional Hazards When Processed:  Handle empty containers with care because residual vapors are flammable.

Precautions for Safe Handling:  Avoid contact with skin, eyes and clothing. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe mist, spray, vapors. Take precautionary measures against static discharge. Use only non-sparking tools.

7.2.       Conditions for Safe Storage, Including Any Incompatibilities 

Technical Measures:  Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical, lighting, ventilating equipment.

Storage Conditions:  Store in a dry, cool, and well-ventilated place. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container closed when not in use. Keep in fireproof place.

Incompatible Materials:  Strong oxidizing agents, acids, alkali metals, ammonia, hydrazine, peroxides, sodium, acid anhydrides, calcium hypochlorite, chromyl chloride, nitrosyl perchlorate, bromine pentafluoride, perchloric acid, silver nitrate, mercuric nitrate, potassium-tert-butoxide, magnesium perchlorate, acid chlorides, platinum, uranium hexafluoride, silver oxide, iodine heptafluoride, acetyl bromide, disulfuryl difluoride, tetrachlorosilane + water, acetyl chloride, permanganic acid, ruthenium (VIII) oxide, uranyl perchlorate, potassium dioxide.

7.3.       Specific End Use(s)  Solvent

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1.       Control Parameters

For substances listed in section 3 that are not listed here, there are no established exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), AIHA (WEEL), NIOSH (REL), or OSHA (PEL).

Ethyl Alcohol (64-17-5)

USA ACGIH

ACGIH chemical category

Confirmed Animal Carcinogen with Unknow Relevance to Humans

USA ACGIH

ACGIH STEL (ppm)

1000 ppm

USA NIOSH

NIOSH REL (TWA) (mg/m³)

1900 mg/m³

USA NIOSH

NIOSH REL (TWA) (ppm)

1000 ppm

USA IDLH

US IDLH (ppm)

3300 ppm

USA OSHA

OSHA PEL (TWA) (mg/m³)

1900 mg/m³

USA OSHA

OSHA PEL (TWA) (ppm)

1000 ppm

 

8.2.       Exposure Controls 

Appropriate Engineering Controls

:

Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Provide sufficient ventilation to keep vapors below permissible exposure limit. Gas detectors should be used when flammable gases/vapors may be released. Proper grounding procedures to avoid static electricity should be followed. Ensure all national/local regulations are observed.

Personal Protective Equipment

:

Gloves. Protective clothing. Protective goggles. Insufficient ventilation: wear respiratory protection.

Gloves Protective Clothing Safety Goggles Respiratory Protection.

Eye Protection

:

Chemical safety goggles or glasses

Skin and Body Protection

:

Wear chemically protective clothing

Respiratory Protection

:

If exposure limits are exceeded or irritation is experienced, approved respiratory protection should be worn.

Other Information

:

Do not eat, drink or smoke during use.

 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1.       Information on Basic Physical and Chemical Properties

Physical State

:

Liquid

Appearance

:

Colorless, clear, volatile liquid

Odor

:

Alcohol

Odor Threshold

:

No data available

pH

:

No data available

Evaporation Rate

:

No data available 

Melting Point

:

No data available 

Freezing Point

:

-113.8 °C (-172.84 °F) 

Boiling Point

:

78 °C (172.4 °F)

Flash Point

:

12.8 °C (55 °F) CC 

Auto-ignition Temperature

:

No data available

Decomposition Temperature

:

No data available 

Flammability (solid, gas)

:

Not applicable 

Lower Flammable Limit

:

3.3 % for Ethanol

Upper Flammable Limit

:

19 % for Ethanol

Vapor Pressure

:

44.6 mm Hg @ 20°C (68°F)

Relative Vapor Density at 20° C

:

1.59 for Ethanol

Relative Density

:

0.8157 – 0.814

Specific Gravity

:

No data available

Solubility

:

Water: Completely 

Partition Coefficient: N-Octanol/Water

:

No data available 

Viscosity

:

No data available 

Explosion Data – Sensitivity to Mechanical Impact

:

Not expected to present an explosion hazard due to mechanical impact.

Explosion Data – Sensitivity to Static Discharge

:

Static discharge could act as an ignition source.

9.2.       Other Information: No additional information available

 

SECTION 10: STABILITY AND REACTIVITY

10.1.       Reactivity:    Reacts violently with strong oxidizers. Increased risk of fire or explosion.

10.2.       Chemical Stability:    Stable at standard temperature and pressure.

10.3.       Possibility of Hazardous Reactions:    Hazardous polymerization will not occur

10.4.       Conditions to Avoid:   Direct sunlight, extremely high or low temperatures, heat, hot surfaces, sparks, open flames, incompatible materials, and other ignition sources.

10.5.       Incompatible Materials:    Strong oxidizing agents, acids, alkali metals, ammonia, hydrazine, peroxides, sodium, acid anhydrides, calcium hypochlorite, chromyl chloride, nitrosyl perchlorate, bromine pentafluoride, perchloric acid, silver nitrate, mercuric nitrate, potassium-tert-butoxide, magnesium perchlorate, acid chlorides, platinum, uranium hexafluoride, silver oxide, iodine heptafluoride, acetyl bromide, disulfuryl difluoride, tetrachlorosilane + water, acetyl chloride, permanganic acid, ruthenium (VIII) oxide, uranyl perchlorate, potassium dioxide.

10.6.       Hazardous Decomposition Products:   Carbon oxides (CO, CO2).

SECTION 11: TOXICOLOGICAL INFORMATION

11.1.       Information on Toxicological Effects

Acute Toxicity: Not classified

Ethyl Alcohol, 200 Proof (64-17-5)

LC50 oral rat

10470 m/kg

LD50 dermal rat 20 ml/kg
LC50 Inhalation rat (ppm) 147.7 mg/I/4h

OSHA Hazard Communication Carcinogen List

In OSHA Hazard Communication Carcinogen list.

 Skin Corrosion/Irritation: Not classified

 Serious Eye Damage/Irritation: Causes serious eye irritation

Respiratory or Skin Sensitization: Not classified

Germ Cell Mutagenicity: Not classified

Teratogenicity: Not Classified

Carcinogenicity: Not classified

Reproductive Toxicity: Not classified

Specific Target Organ Toxicity (Single Exposure): Not classified

Specific Target Organ Toxicity (Repeated Exposure): Not classified

Aspiration Hazard: Not classified

Symptoms/Injuries After Inhalation: Prolonged exposure to liquid may cause a mild irritation.

Symptoms/Injuries After Skin Contact: Repeated or prolonged skin contact may cause dermatitis and defatting

Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms may include: Redness, pain, swelling, itching, burning, tearing, and blurred vision

Symptoms/Injuries After Ingestion: Ingestion will cause narcotic effects including, but not limited to: nausea, vomiting, abdominal pain, dizziness, incoordination, and respiratory depression

Chronic Symptoms: None expected under normal conditions of use

 

SECTION 12: ECOLOGICAL INFORMATION

12.1.       Toxicity 

Ecology - General: Readily bioldegrades. Evaporates to moderate extent. Does not bioaccumulate

Ethyl alcohol (64-17-5)

LC50 Fish 1

12.0 - 16.0 ml/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static])

EC50 Daphnia 1

9268 - 14221 mg/l (Exposure time: 48 h - Species: Daphnia magna)

LC 50 Fish 2

> 100 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])

 

12.2.       Persistence and Degradability 

Ethyl Alcohol (64-17-5)

Persistence and Degradability

Not established. May cause long-term adverse effects in the environment.

 

12.3.       Bioaccumulative Potential 

Ethyl Alcohol (64-17-5)

Bioaccumulative Potential

Not established.

Log Pow

-0.32

 

12.4.       Mobility in Soil  No additional information available

12.5.       Other Adverse Effects

Other Information

:

Avoid release to the environment.

 

SECTION 13: DISPOSAL CONSIDERATIONS

13.1.       Waste Treatment Methods 

Waste Disposal Recommendations:  Dispose of contents/container in accordance with local, regional, national, and international regulations.

Additional Information:  Handle empty containers with care because residual vapors are flammable.

Ecology - Waste Materials:  Avoid release to the environment. This material is hazardous to the aquatic environment. Keep out of sewers and waterways.

 

SECTION 14: TRANSPORT INFORMATION

In Accordance with DOT      

Proper Shipping Name

:

ETHYL ALCOHOL SOLUTIONS

Hazard Class : 3
Identification No. : UN1170
Label Codes: : 3
Packing group : II

Marine Pollutant

:

Marine pollutant

ERG Number

:

127

 

 

 

Transport by sea

In Accordance with IMDG

Proper Shipping Name

:

ETHYL ALCOHOL SOLUTIONS

Hazard Class : 3
Identification No. : UN1170
Label Codes: : 3
Packing group : II

Marine Pollutant

:

Marine pollutant

EmS-No. (Fire)

:

F-E

EmS-No. (Spillage)

:

S-D

 

 Air transport

In Accordance with IATA

Proper Shipping Name

:

ETHYL ALCOHOL SOLUTIONS

Hazard Class : 3
Identification No. : UN1170
Label Codes: : 3
Packing group : II

ERG Code (IATA)

:

3L

 

 

 

 

 

 

SECTION 15: REGULATORY INFORMATION

15.1.       US Federal Regulations 

Ethyl Alcohol, 200 Proof (64-17-5)

Listed on the United States TSCA (Toxic Substances Control Act) inventory

SARA Section 311/312 Hazard Classes

Fire Hazard

Immediate (acute) health hazard


Ethyl alcohol (64-17-5)

Listed on the United States TSCA (Toxic Substances Control Act) inventory

 

15.2.       US State Regulations 

Ethyl alcohol (64-17-5)

U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List


Ethyl Alcohol  (64-17-5)

U.S. - California - Proposition 65 - Carcinogens List

WARNING: This product contains chemicals known to the State of California to cause cancer. Ethyl Alcohol is included on the Proposition 65 list when it is used in alcoholic beverages.

U.S. - California - Proposition 65 - Developmental Toxicity

WARNING: This product contains chemicals known to the State of California to cause birth defects. Ethyl Alcohol is included on the Proposition 65 list when it is used in alcoholic beverages.

 

SECTION 16: OTHER INFORMATION

Date of Preparation or Latest Revision

:

04/04/2016

Other Information

:

This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200

 

GHS Full Text Phrases:

Eye Irrit. 2A

Serious eye damage/eye irritation Category 2A

Flam. Liq. 2

Flammable liquids Category 2

H225

Highly flammable liquid and vapor

H319

Causes serious eye irritation

 

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

SDS US (GHS HazCom)